Windows PE loads USB storage devices after the local drives and before virtual drives. For a quick overview (which may be different on any system, no guarantees here) that would be:
$0$0
$0
$0HDD 0: Partition 1: C:\(Depends on your answer file / diskpart procedure)$0
$0HDD 0: Partition 2: D:\(Depends on your answer file / diskpart procedure)$0
$0CDROM 0 / USB 0: E:\ (This is the contents of the drive that booted Windows PE)$0
$0Virtual Drive 0: X:\ (Contains the virtual image of the Window
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